4-Chloro-N-(2,5-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide

نویسندگان

  • Vinola Z. Rodrigues
  • Sabine Foro
  • B. Thimme Gowda
چکیده

The asymmetric unit of the title compound, C(15)H(16)ClNO(2)S, contains three independent moleules. The conformation of the N-H bonds are anti to the ortho-methyl groups of the sulfonyl benzene rings in all the mol-ecules. The sulfonyl and the aniline benzene rings are tilted relative to each other by 43.0 (2), 37.0 (2) and by 46.0 (1)° in the three mol-ecules. In the crystal, inter-molecular N-H⋯O hydrogen bonds link each of the mol-ecules into centrosymmetric dimers.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

4-Chloro-N-(2,4-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(15)H(16)ClNO(2)S, the C-SO(2)-NH-C torsion angle is 67.45 (17)°. The two aromatic rings are tilted relative to each other by 44.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds..

متن کامل

4-Chloro-N-(2,6-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(15)H(16)ClNO(2)S, the C-SO(2)-NH-C torsion angle is -61.15 (16)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 38.8 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

متن کامل

N-(2,5-Dimethyl­phen­yl)-4-methyl­benzene­sulfonamide

In the crystal structure of the title compound, C(15)H(17)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -61.0 (2)°. The dihedral angle between the two aromatic rings is 49.4 (1)°. The crystal structure features inversion-related dimers linked by pair...

متن کامل

4-Chloro-N-(3,4-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(15)H(16)ClNO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the meta-methyl group in the aniline benzene ring and the ortho-methyl group in the sulfonyl benzene ring. The C-SO(2)-NH-C torsion angle is -49.72 (18)°. The sulfonyl and aniline...

متن کامل

4-Chloro-N-(2,5-dimethyl­phen­yl)benzene­sulfonamide

The title compound, C(14)H(14)ClNO(2)S, contains two molecules in the asymmetric unit with different conformations. The C-SO(2)-NH-C torsion angles are 65.3 (2) and 54.6 (2)° and the aromatic rings are tilted relative to each other by 59.3 (1) and 45.8 (1)° in the two mol-ecules. In the crystal, inversion symmetry results in dimers linked by pairs of N-H⋯O hydrogen bonds for both molecules.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011